In 1967, the original Walker Branch Watershed (WBW) project was established to study elemental cycling and mass balances in a relatively unimpacted watershed. Over the next 50+ years, findings from additional experimental studies and longāterm observations on WBW advanced understanding of catchment hydrology, biogeochemistry, and ecology and established WBW as a seminal site for catchment science. The 97.5āha WBW is located in East Tennessee, USA, on the U.S. Department of Energy's Oak Ridge Reservation. Vegetation on the watershed is characteristic of an eastern deciduous, secondāgrowth forest. The watershed is divided into two subcatchments: the West Fork (38.4 ha) and the East Fork (59.1 ha). Headwater streams draining these subcatchments are fed by multiple springs, and thus flow is perennial. Stream water is high in base cations due to weathering of dolomite bedrock and nutrient concentrations are low. Longāterm observations of climate, hydrology, and biogeochemistry include daily (1969ā2014) and 15āmin (1994ā2014) stream discharge and annual runoff (1969ā2014); hourly, daily, and annual rainfall (1969ā2012); daily climate and soil temperature (1993ā2010); and weekly stream water chemistry (1989ā2013). These longāterm datasets are publicly available on the WBW website (https://walkerbranch.ornl.gov/longātermādata/). While collection of these data has ceased, related longāterm measurements continue through the National Ecological Observatory Network (NEON), where WBW is the core terrestrial and aquatic site in the Appalachian and Cumberland Plateau region (NEON's Domain 7) of the United States. These longāterm datasets have been and will continue to be important in evaluating the influence of climatic and environmental drivers on catchment processes.