October 2009

Journal

A Concise Approach to the Synthesis of opp-Dibenzoporphyrins through the Heck Reaction

By:
Deshpande, Rohit; Jiang, Lin; Schmidt, Gregory; Rakovan, John; Wang, Xiaoping ; Wheeler, Kraig; Wang, Hong
Journal Name:
Organic Letters
Page Number:
4251-4253
Volume:
11
Issue Number:
19
Publication Date:
October 19, 2009
View DOI Listing:
https://doi.org/10.1021/ol901615f

Abstract

A concise approach to the synthesis of functionalized opp-dibenzoporphyrins is described. In this method, introduction of alkenyl groups to the porphyrin periphery through the vicinal 2-fold Heck reaction, 6-Ï€ electrocyclization, and subsequent aromatization occur in one pot.


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