November 2023

Journal

Determination of phosphorus and sulfur in uranium ore concentrates by triple quadrupole inductively coupled plasma mass spectrometry

By:
Fletcher, Nathaniel D; Manard, Benjamin T; Bostick, Debra A; Bostick, William D; Metzger, Shalina C; Ticknor, Brian W; Rogers, Kayron N; Hexel, Cole R
Journal Name:
Talanta
Page Number:
121573
Volume:
221
Issue Number:
1
Publication Date:
November 9, 2023
View DOI Listing:
https://doi.org/10.1016/j.talanta.2020.121573

Abstract

The analysis of impurities in a uranium ore concentrate (UOC) could provide information regarding the source, production history, and potential intended use of the UOC. This study involves the analysis of UOC samples for phosphorus and sulfur. Concentrations were determined by triple quadrupole inductively coupled plasma – mass spectrometry and compared with results from a pyrohydrolysis method as well as previously reported results. The sulfur and phosphorus concentrations, determined by the mass spectrometer, were used to explore possible trends in a series of UOC material, and the uncertainties were calculated using GUM workbench software. The triple quadrupole inductively coupled plasma – mass spectrometer method allows for the removal of interferences in the analysis of species.